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Seawater

An aqueous solution of salts of a rather constant composition of elements whose presence determines the climate and makes life possible on the Earth and which constitutes the oceans, the mediterranean seas, and their embayments. The physical, chemical, biological, and geological events therein are the studies that are grouped as oceanography. Water is most often found in nature as seawater (about 98%). The rest is ice, water vapor, and fresh water. The basic properties of seawater, their distribution, the interchange of properties between sea and atmosphere or land, the transmission of energy within the sea, and the geochemical laws governing the composition of seawater and sediments are the fundamentals of oceanography. Hydrosphere Oceanography

Major constituents of seawater (salinity 35 psu)*

 

Amount,

 

Amount,

Positive ions

g/kg

Negative ions

g/kg

Sodium (Na+)

10.752

Chloride (Cl-)

19.345

Magnesium (Mg2+)

1.295

Bromide (Br-)

0.066

Potassium (K+)

0.390

Fluoride (F-)

0.0013

Calcium (Ca2+)

0.416

Sulfate (SO4-)

2.701

Strontium (Sr2+)

0.013

Bicarbonate

0.145

 

 

(HCO3-)

 

 

 

Boron hydroxide

0.027

 

 

(B(OH)3-)

 

*Water, 965 psu; dissolved materials, 35 psu.

The major chemical constituents of seawater are cations (positive ions) and anions (negative ions) [see table]. In addition, seawater contains the suspended solids, organic substances, and dissolved gases found in all natural waters. A standard salinity of 35 practical salinity units (psu; formerly parts per thousand, or ‰) has been assumed. While salinity does vary appreciably in oceanic waters, the fractional composition of salts is remarkably constant throughout the world's oceans. In addition to the dissolved salts, natural seawater contains particulates in the form of plankton and their detritus, sediments, and dissolved organic matter, all of which lend additional coloration beyond the blue coming from Rayleigh scattering by the water molecules. Almost every known natural substance is found in the ocean, mostly in minute concentrations.

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From McGraw-Hill Concise Encyclopedia of Environmental Science. The Content is a copyrighted work of McGraw-Hill and McGraw-Hill reserves all rights in and to the Content. The Work is © 2008 by The McGraw-Hill Companies, Inc.
 

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